Two-dimensional phase transition mediated by extrinsic defects

 

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A. V. Melechko, J. Braun, H. H. Weitering, and E. W. Plummer

Department of Physics and Astronomy, The University of Tennessee, Knoxville, Tennessee 37996
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831

(Received 22 February 1999)

We have investigated the (sqrt(3)×sqrt(3) ) to (3×3) phase transition in the alpha phase of Sn/Ge(111) with variable temperature STM at temperatures between 30 and 300 K. Point defects in the Sn film stabilize localized regions of the (3×3) phase, where the size is characterized by a temperature dependent length (exponential attenuation). The inverse of the attenuation length is a linear function of temperature showing that the phase transition occurs at 70 K. At low temperature a density wave mediated defect-defect interaction realigns the defects to be in registry with the (3×3) domains.

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